BLTMG - TRICHLOROACETIC ACID CRYSTALLINE, T4885

  • MSDS: BLTMG
  • Manufacturer: SIGMA CHEMICAL CO
  • Product Name: TRICHLOROACETIC ACID CRYSTALLINE, T4885
  • National Stock Number: 6810-00N021915
Product Identification

Product ID:TRICHLOROACETIC ACID CRYSTALLINE, T4885
MSDS Date:03/19/1990
FSC:6810
NIIN:00N021915
MSDS Number: BLTMG

Responsible Party
SIGMA CHEMICAL CO
ST LOUIS, MO 63178
US

Emergency Phone: 314-771-5765

Info Phone: 800-325-3010

Cage: 21076

Contractor
SIGMA CHEMICAL COMPANY
14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

Ingredients

ACETIC ACID, TRICHLORO-; (TRICHLOROACETIC ACID)

CAS: 76-03-9

RTECS: AJ7875000

OSHA PEL 1 PPM

ACGIH TLV: 1 PPM

Hazards

LD50 LC50 Mixture:LD50:(ORAL RAT) 400 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED, INHALED OR
ABSORBED THRU SKIN. MATL IS EXTREMELY DESTRUCTIVE TO TISS OF THE
MUC MEMB & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE FATAL AS A
RSLT OF SPASM, INFLAM & EDEMA OF THE LARYNX & BRONCHI, CHEM PNEUM
& PULM EDEMA. SYMPS OF EXPOS MY INCL BURNING SENSATION, (SEE EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:COUGHING, WHEEZING, LARYNGITIS,
SHORTNESS OF BREATH, HEADACHE, NAUSEA & VOMITING. CAUSES BLISTERS
ON CONTACT W/SKIN. CHRONIC:GASTROINTESTINAL DISTURBANCES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid

First Aid:EYE/SKIN:IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. ASSURE ADEQUATE
FLUSHING OF THE EYES BY SEPARATING THE EYELIDS W/FINGERS. WASH
CONTAMIN ATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED SHOES.
INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTF RESP. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A MD. INGEST:CALL MD
IMMED .

Fire Fighting

Flash Point:>230
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Accidental Release

Spill Release Procedures:WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES.
COVER W/DRY LIME OR SODA ASH & PICK UP. KEEP IN A CLOSED CONTAINER
& HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH SPILL SITE AFTER
MATERIAL PICKUP IS C OMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP
TIGHTLY CLOSED. AVOID PROLONGED/REPEATED EXPOSURE. DO NOT GET IN
EYES, ON SKIN OR ON CLOTHING. DO NOT BREATHE DUST.
Other Precautions:TOXIC. VESICANT. CORROSIVE. VERY HYGROSCOPIC.

Exposure Controls

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE
BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

Chemical Properties

HCC:C1
Boiling Pt:B.P. Text:385F,196C
Melt/Freeze Pt:M.P/F.P Text:129F,54C
Vapor Pres:1 MM @ 51C
Vapor Density:<1
Spec Gravity:1.620
Appearance and Odor:WHITE CRYSTALLINE POWDER.

Stability

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS & STRONG BASES.
Stability Condition to Avoid:PROTECT FROM MOISTURE.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE & HYDROGEN CHLORIDE GAS.

Disposal

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL W/A COMBUSTIBE
SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER
& SCRUBBER. OBSERVE ALL FEDERAL, STATE & LOCAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.